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DP IB Chemistry: HL

Topic Questions

Home / IB / Chemistry: HL / DP / Topic Questions / 20. Organic Chemistry (HL only) / 20.2 Synthetic Routes / Multiple Choice: Paper 1


20.2 Synthetic Routes

Question 1

Marks: 1

The equation below shows the conversion of propanal to propyl ethanoate.

formation-of-ester-from-aldehyde   What are the reagents used and the reactions taking place?

  Reaction 1  Reagents 1 Reaction 2 
A

oxidation

K2Cr2O7 and H2SO4

nucleophilic substitution (condensation) 

B

reduction

 NaBH4

nucleophilic substitution (condensation)

C

reduction

 LiAlH4

oxidation

D

hydrogenation

H2

addition

    Choose your answer
      

    Question 2

    Marks: 1

    But-1-ene reacts separately with HBr and H2/ Ni to give products X and Z respectively. 

    What are the major products of the reactions?

      X Z
    A. CH2BrCH2CH2CH3 CH3CH2Cidentical toCH
    B. CH3CH2CH2CH2OH CH3CH2CH2CH3
    C. CH3CHBrCH2CH3 CH3CH2Cidentical toCH
    D. CH3CHBrCH2CH3 CH3CH2CH2CH3

      Choose your answer
        

      Question 3

      Marks: 1

      Methylbenzene can be converted into 4-methylphenylamine in a multi-step reaction.

      Which order should the reagents be used to do this conversion? 

        1st reagent 2nd reagent 3rd reagent
      A. conc. HNO/ conc. H2SO4 Sn / conc. HCl  NaOH
      B. Sn / conc. HCl conc. HNO/ conc. H2SO4  NaOH
      C. Sn / conc. HCl  NaOH conc. HNO/ conc. H2SO4
      D.  NaOH conc. HNO/ conc. H2SO4 Sn / conc. HCl
        Choose your answer
          
        Key Concepts
        Organic Synthesis

        Question 4

        Marks: 1

        Which alcohol could not be produced by the reduction of an aldehyde or a ketone?

        • 2,2-Dimethylbutan-1-ol

        • Propan-2-ol

        • 3-Methylpentan-3-ol

        • 2-Methylpentan-3-ol

        Choose your answer
          

        Question 5

        Marks: 1

        Which molecule(s) can be both reduced by sodium borohydride, NaBH4, and oxidised by warm acidified potassium dichromate (VI)? 

        1. CH3CHBr(CH3)2CCHO
        2. CH3CHOHCH2CH3
        3. (CH3)3CCHO

        • I and II only 

        • I and III only 

        • II and III only 

        • I, II and III 

        Choose your answer
          
        Key Concepts
        Organic Synthesis