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DP IB Chemistry: HL

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Home / IB / Chemistry: HL / DP / Topic Questions / 19. Redox Processes (HL only) / 19.1 Electrochemical Cells / Structured Questions: Paper 2


19.1 Electrochemical Cells

Question 1a

Marks: 1
a)
The image below shows a half cell that can be used to calculate the standard electrode potential of the Fe2+ / Fe reaction.
 
1-21
State the half equation, including state symbols, that represents this half cell.
[1]
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    Key Concepts
    Electrochemical Cells

    Question 1b

    Marks: 3
    b)
    The electrochemical cell that is used to measure the standard electrode potential of the Fe2+ / Fe electrode is shown below.
    IB Chem 19.1 HL SQ E Q1c SHE set up

    State the cell representation for the electrochemical cell set up using the standard hydrogen electrode and the Fe2+ / Fe electrode.
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      Question 1c

      Marks: 2
      c)
      Explain why platinum is used as the electrode for the standard hydrogen electrode.
      [2]
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        Question 1d

        Marks: 4
        d)
        The image shows the electrochemical cell used to measure the standard electrode potential, EΘ , for the Cl2 / Clhalf cell. 

        3-1

        i)
        Write the conventional cell representation for this electrochemical cell. 
        [3]
        ii)

        Determine the standard electrode potential, EӨ, for the Cl2 / Cl- half cell.

        [1]

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          Question 2a

          Marks: 1
          a)
          State the equation that is required to determine the electromotive force (EMF). 
          [1]
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            Question 2b

            Marks: 3
            b)
            Use section 24 of the data booklet to calculate the electromotive force, in volts, of the following cells.

            i)
            Zn (s) | Zn2+ (aq) || Cu2+ (aq) | Cu (s) 
            [1]

            ii)
            Mg (s) | Mg2+ (aq) || Ag(aq) | Ag (s) 
            [1]

            iii)
            Pt (s) | Fe2+ (aq) , Fe3+ (aq) || Cl2 (g), 2Cl- (aq) | Pt (s)
            [1]

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              Question 2c

              Marks: 4
              c)
              A voltaic cell is constructed using the Ag / Ag half cell and Pb / Pb2+. Use section 24 of the data booklet to state the following. Include state symbols in your equations. 

              Half equation for the Ag / Ag+ half cell ……………………………………………………………………………………..
              [1]

              Half equation for the Pb / Pb2+ half cell ……………………………………………………………………………………..
              [1]

              Overall equation for the voltaic cell ……………………………………………………………………………………..
              [2]
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                Question 2d

                Marks: 1
                d)
                Use section 24 of the data booklet to determine the electromotive force of the voltaic cell outlined in part c). 
                [1]
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                  Question 3a

                  Marks: 6
                  a)
                  Use section 24 of the data booklet to answer the following questions about the electrolysis of dilute sodium chloride solution using inert electrodes.

                  i)
                  State the equations to generate the ions present in solution. 
                  [2]

                  ii)
                  Predict the product at the anode.
                  [2]

                  iii)
                  Predict the product at the cathode.
                  [2]
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                    Question 3b

                    Marks: 6
                    b)
                    Use section 24 of the data booklet to predict the products at the anode and cathode for the electrolysis of copper sulfate with inert electrodes.

                    i)
                    State the equations to generate the ions present in solution.
                    [2]

                    ii)
                    Predict the product at the anode.
                    [2]

                    iii)
                    Predict the product at the cathode.
                    [2]
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                      Question 3c

                      Marks: 3
                      c)
                      Use your answer to part b) to write an overall equation for the electrolysis of copper sulfate using inert electrodes.
                      [3]
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                        Question 3d

                        Marks: 2
                        d)
                        The inert electrodes for the electrolysis of copper sulfate are replaced by copper electrodes. State the half equations that occur at the anode and cathode that occur with copper electrodes.

                        [2]

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                          Question 4a

                          Marks: 1
                          a)
                          State the equation which can be used to determine charge in coulombs, C.
                          [1]
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                            Question 4b

                            Marks: 5
                            b)
                            During the electrolysis of silver nitrate a current of 0.10 amps is run for ten minutes. Use section 2 and 6 of the data booklet to determine the following.

                            i)
                            The number of coulombs.
                            [1]

                            ii)
                            The number of Faradays.
                            [1]

                            iii)
                            The half equation for the formation of silver metal from silver ions.
                            [1]

                            iv)
                            The amount of silver, in moles.
                            [1]

                            v)
                            The mass of silver, in grams, deposited after ten minutes.
                            [1]
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                              Question 4c

                              Marks: 5
                              c)
                              A solution of copper sulfate, CuSO4 (aq), is electrolysed for 20 mins at a current of 1.50 A. Use sections 2 and 6 of the data booklet to determine the following.

                              i)
                              The number of coulombs.
                              [1]

                              ii)
                              The number of Faradays.
                              [1]

                              iii)
                              The half equation for the formation of copper metal from copper ions.
                              [1]

                              iv)
                              The amount of copper, in moles.
                              [1]

                              v)
                              The mass of copper, in grams, deposited after ten minutes.
                              [1]
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                                Question 4d

                                Marks: 1
                                d)
                                A student sets up apparatus to electroplate a metal spoon with copper. The student chose to use copper as the anode and the spoon as the cathode. Is the student correct to do so?

                                [1]

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                                  Key Concepts
                                  Electroplating

                                  Question 5a

                                  Marks: 1
                                  a)
                                  State the value above which the value for the standard electrode potential, Eθcell  value , indicates a reaction is spontaneous. 
                                  [1]
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                                    Key Concepts
                                    Free Energy & Eº

                                    Question 5b

                                    Marks: 2
                                    b)

                                    The spontaneous reaction between zinc and copper in a voltaic cell is shown below

                                    Ni (s) +  Cu2+ (aq) → Ni2+ (aq)  +  Cu (s)          Eθ cell = +0.60 V

                                    Use sections 1 and 2 of the data booklet to determine the free energy change, ΔGθ, for the reaction in kJ mol-1

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                                      Key Concepts
                                      Free Energy & Eº

                                      Question 5c

                                      Marks: 4

                                      c) Use section 24 of the data booklet to determine if the reaction shown is spontaneous at standard conditions

                                      Pb (s) + Mg2+ (aq)  → Pb2+ (aq) + Mg (s)

                                      [4]

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