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DP IB Chemistry: HL

Topic Questions

Home / IB / Chemistry: HL / DP / Topic Questions / 18. Acids & Bases (HL only) / 18.1 Further Aspects of Acids & Bases / Structured Questions: Paper 2


18.1 Further Aspects of Acids & Bases

Question 1a

Marks: 3
a)
Define the terms Lewis acid and Lewis base and state the type of bond formed between a Lewis acid and base.

[3]

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    Question 1b

    Marks: 5
    b)
    Identify which of the following are Lewis acids, Lewis bases or neither:
    NH3, K+, SO42-, CH4, BCl3

    [5]

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      Question 1c

      Marks: 2
      c)
      Explain why aqueous ions of transition metals can act as Lewis acids.

      [2]

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        Question 1d

        Marks: 1
        d)
        State an alternative name for a species that acts as a Lewis base in organic chemistry mechanisms.

        [1]

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          Question 2a

          Marks: 2
          a)
          On the axes below, draw a sketch graph to show the neutralisation of ethanoic acid by sodium hydroxide:
          U7Pfi2Bz_q2-18-1-sq-hl

          [2]

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            Key Concepts
            pH Curves

            Question 2b

            Marks: 2
            b)
            Write an equation for the reaction between ethanoic acid and sodium hydroxide and identify the species acting as a Lewis base in the reaction.

            [2]

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              Key Concepts
              pH Curves

              Question 2c

              Marks: 2
              c)
              Identify the type of titration taking place from the curve and indicate where the buffer region is found on this curve.
              q3-18-1-sq-hl-answer
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                Key Concepts
                pH Curves
                Buffers

                Question 2d

                Marks: 2
                d)
                Identity on the graph the point at which pKa= pH and find the pKa of the acid.

                2-2

                [2]

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                  Key Concepts
                  pH Curves

                  Question 3a

                  Marks: 3
                  a)
                  Explain how an acid-base indicator works.

                  [3]

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                    Key Concepts
                    Indicators

                    Question 3b

                    Marks: 2
                    b)
                    Phenolphthalein, C20H14O4, is an acid-base indicator. State the formula and colour of the conjugate base of phenolphthalein.

                    [2]

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                      Key Concepts
                      Indicators

                      Question 3c

                      Marks: 3
                      c)
                      Explain how suitable indicators are chosen for titrations.

                      [3]

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                        Key Concepts
                        Indicators

                        Question 4a

                        Marks: 1
                        a)
                        Outline what is meant by a buffer solution.

                        [1]

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                          Key Concepts
                          Buffers

                          Question 4b

                          Marks: 2
                          b)
                          Outline how a buffer solution can be made starting from 1.0 mol dm-3 ethanoic acid and 1.0 mol dm-3 sodium hydroxide.

                          [2]

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                            Key Concepts
                            Buffers

                            Question 4c

                            Marks: 4
                            c)
                            Use suitable equations to explain how the buffer in b) functions when a small quantity of acid is added.

                            [4]

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                              Key Concepts
                              Buffers

                              Question 4d

                              Marks: 1
                              d)
                              State the composition of a basic buffer.

                              [1]

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                                Key Concepts
                                Buffers

                                Question 5a

                                Marks: 1
                                a)
                                Explain what is meant by the term hydrolysis in acids and bases.

                                [1]

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                                  Key Concepts
                                  Salt Hydrolysis

                                  Question 5b

                                  Marks: 3
                                  b)
                                  Salts can be acidic, basic or neutral. Explain how you can predict whether a salt is likely to be acidic. Include an equation in your answer.

                                  [3]

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                                    Key Concepts
                                    Salt Hydrolysis

                                    Question 5c

                                    Marks: 3
                                    c)
                                    Deduce which of the following salts are acidic, basic or neutral:
                                                                                 CH3COONa; NH4Cl; KCl

                                    [3]

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                                      Key Concepts
                                      Salt Hydrolysis