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DP IB Chemistry: HL

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Home / IB / Chemistry: HL / DP / Topic Questions / 20. Organic Chemistry (HL only) / 20.2 Synthetic Routes / Structured Questions: Paper 2


20.2 Synthetic Routes

Question 1a

Marks: 4
a)
An organic reaction sequence is shown below.

q1a_20-2_ib_hl_medium_sq

  

State the IUPAC names of the four substances in the sequence.
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    Key Concepts
    Organic Synthesis

    Question 1b

    Marks: 6
    b)
    Classify the reactions in (a) and give the names of the reagents in each step.
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      Key Concepts
      Organic Synthesis

      Question 1c

      Marks: 1
      c)

      Give the reaction conditions for step 3 in (a)

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        Key Concepts
        Organic Synthesis

        Question 1d

        Marks: 1
        d)

        Draw a displayed formula of an isomer of C4H10O that gives two signals in an 1H NMR spectrum.

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          Question 2a

          Marks: 3
          a)

          The following reaction pathway is used to produce Compounds A and B, which when reacted together, form a branched ester molecule, Compound C

          Suggest suitable reagents and conditions for the synthesis of Compound A via Step 1 and give the name for this type of reaction.

          q2a_20-2_ib_hl_medium_sq

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            Key Concepts
            Organic Synthesis

            Question 2b

            Marks: 4
            b)
            In order for the ester to be produced, the ketone in part (a) must be converted to another compound, B.

             

            i)
            Name and draw the structure of the molecule that is produced from Step 2.

             

            ii)
            Give the name of the type of reaction that is involved in Step 2 and suggest suitable reagents and conditions for the process.
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              Key Concepts
              Organic Synthesis

              Question 2c

              Marks: 6
              c)

              Outline how ethanol can be synthesised from ethane in two steps. State the reaction conditions and reagents and name the type of reaction taking place.

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                Key Concepts
                Organic Synthesis

                Question 2d

                Marks: 3
                d)
                The four step synthesis to form propan-1-ol from a ketone is outlined below.

                q2d_20-2_ib_hl_medium_sq

                  

                i)
                Give the names of four possible substances A to D
                 
                ii)
                Give the reagents and conditions for Step 4.
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                  Key Concepts
                  Organic Synthesis

                  Question 3a

                  Marks: 2
                  a)

                  Propanal is a versatile organic building block used in the synthesis of plastics and rubber chemicals.

                  Propanal can be produced from propanoic acid in the following two-step reaction. 

                   

                  Step 1

                   

                  Step 2

                   

                  Propanoic acid

                  q3a_20-2_ib_hl_medium_sq

                  Propan-1-ol

                  q3a1_20-2_ib_hl_medium_sq

                  Propanal

                  State the reaction type, including suitable reagents, for Steps 1 and 2.

                   

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                    Key Concepts
                    Organic Synthesis

                    Question 3b

                    Marks: 1
                    b)
                    Suggest why it is not possible to convert propanoic acid directly to propanal using the reagent you identified for Step 1 in (a).
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                      Key Concepts
                      Organic Synthesis

                      Question 3c

                      Marks: 1
                      c)

                      Explain why Step 2, in (a), is completed by distillation.

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                        Question 3d

                        Marks: 2
                        d)

                        Identify, explain your reasoning, which of the three organic compounds, from the reaction scheme in (a), would be distilled first.

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                          Key Concepts
                          Intermolecular forces

                          Question 4a

                          Marks: 3
                          a)
                          State four factors that should be considered when designing a reaction scheme for the synthesis of a target molecule in industry.
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                            Key Concepts
                            Organic Synthesis

                            Question 4b

                            Marks: 2
                            b)
                            1-(3-Aminophenyl)ethanol can be synthesised according to the following three-step reaction scheme.

                            q4b_20-2_ib_hl_medium_sq

                             

                            Step 1 involves a reaction at position 3 of the benzene ring of 1-phenylethan-1-one. 
                             
                            State the reaction type, including suitable reagents, for Step 1.

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                              Key Concepts
                              Organic Synthesis

                              Question 4c

                              Marks: 1
                              c)
                              State a suitable reagent for Step 2, in (b).
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                                Key Concepts
                                Organic Synthesis

                                Question 4d

                                Marks: 2
                                d)

                                In Step 3 of the reaction scheme from (b), compound C is heated with hydrochloric acid in the presence of a tin catalyst to form the final product, 1-(3-aminophenyl)ethanol. 

                                Explain why Step 3 is a reduction reaction.

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                                  Question 5a

                                  Marks: 2
                                  a)

                                  Suggest a reaction scheme, using displayed formulae, that could be used to prepare a sample of propyl propanoate. 

                                  Conditions and reagents are not required.

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                                    Key Concepts
                                    Organic Synthesis

                                    Question 5b

                                    Marks: 2
                                    b)
                                    One of the intermediates in the reaction scheme, from (a), has a molecular mass of 74.09 g mol-1.
                                     
                                    i)
                                    State suitable reagents and conditions required to form this intermediate. 

                                    ii)
                                    Describe how you could test that this intermediate has been formed.
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                                      Key Concepts
                                      Organic Synthesis

                                      Question 5c

                                      Marks: 2
                                      c)

                                      Propanal and the intermediate (Mr = 74.09) in the reaction scheme, from (a), are to be separated by distillation.

                                      Explain which chemical will distil first.

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                                        Key Concepts
                                        Organic Synthesis

                                        Question 5d

                                        Marks: 2
                                        d)
                                        One of the intermediates in the reaction scheme, from (a), has a molecular mass of 60.09 g mol-1. 

                                        i)
                                        State suitable reagents and conditions required to form this intermediate. 

                                        ii)
                                        Using Section 26 of the Data Booklet, describe how you could prove that this intermediate has been formed without reversing the reaction.
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                                          Key Concepts
                                          Organic Synthesis