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DP IB Chemistry: HL

Topic Questions

Home / IB / Chemistry: HL / DP / Topic Questions / 13. The Periodic Table- Transition Metals (HL only) / 13.1 Transition Metals / Structured Questions: Paper 2


13.1 Transition Metals

Question 1a

Marks: 2
a)
Transition metals can form complex ions where ligands are coordinately bonded to the central metal ion.

i)    Define the term ligand.

[1]

ii)    State what is meant by the term bidentate ligand

[1]

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    Key Concepts
    Complex Ions

    Question 1b

    Marks: 2
    b)
    Transition metals are located in the d-block of the periodic table.

    i)
    State the electron configuration of V2+.

    [1]

    ii)
    Explain why scandium is not considered a transition metal.

    [1]

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      Question 1c

      Marks: 1
      c)

      State the oxidation state of Fe in [Fe(CN)6]4−.

      [1]

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        Question 1d

        Marks: 3
        d)
        Iron and zinc are in the d-block of the Periodic Table. Iron(II) ions, [Fe(H2O)6]2+, form a pale green solution but zinc ions,   [Zn(H2O)6]2+, form a colourless solution.

        i)
        Write the electron configuration of Zn2+.
        [1]
        ii)
        Explain why zinc ions are colourless.
        [2]
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          Question 2a

          Marks: 1
          a)

          A complex ion contains one Fe3+ ion, four ammonia molecules and two chloride ions.

          State the formula of this complex ion.

          [1]

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            Key Concepts
            Complex Ions

            Question 2b

            Marks: 2
            b)
            State two characteristic properties of transition elements.
            [2]
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              Key Concepts
              Transition Elements

              Question 2c

              Marks: 1
              c)

              Transition metals can be used as successful catalysts in a range of reactions.

              State what is meant by the term homogeneous catalyst.
              [1]
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                Key Concepts
                Catalytic Properties

                Question 2d

                Marks: 2
                d)

                Transition metals can form complexes with different ligands.

                Identify one species from the following list that does not act as a ligand and explain your answer.


                CO         H2O         SCN-          H2
                [2]
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                  Key Concepts
                  Complex Ions

                  Question 3a

                  Marks: 1
                  a)

                  Using section 16 of the data booklet, state the formula of a bidentate ligand.

                  [1]

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                    Key Concepts
                    Complex Ions

                    Question 3b

                    Marks: 3
                    b)
                    State three factors that affect the value of the splitting energy, ΔE, in the d-orbitals.
                    [3]
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                      Question 3c

                      Marks: 5
                      c)
                      Outline why transition metals form coloured compounds.

                      [5]

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                        Key Concepts
                        Crystal Field Theory

                        Question 3d

                        Marks: 2
                        d)
                        Using section 15 of the data booklet, explain why adding ammonia to aqueous copper(II) ions results in a darker blue complex.
                        [2]
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                          Question 4a

                          Marks: 1
                          a)
                          Deduce the oxidation state of vanadium in the compound NH4VO3.
                          [1]
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                            Question 4b

                            Marks: 1
                            b)
                            Transition elements can be used to catalyse certain reactions.
                            Define the term heterogeneous in relation to catalysts.
                            [1]
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                              Key Concepts
                              Catalytic Properties

                              Question 4c

                              Marks: 1
                              c)
                              Outline the difference between diamagnetic and paramagnetic elements in terms of electron arrangement.
                              [1]
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                                Key Concepts
                                Magnetic Properties

                                Question 4d

                                Marks: 1
                                d)
                                Describe the splitting of the d orbitals in an octahedral crystal field.
                                [1]
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                                  Key Concepts
                                  Crystal Field Theory