Which of the following conditions will mean a reaction is never feasible?
|
ΔH
|
ΔS
|
Temperature
|
A
|
Negative
|
Positive
|
High
|
B
|
Positive
|
Negative
|
High
|
C
|
Negative
|
Negative
|
Low
|
D
|
Positive
|
Positive
|
High
|
Ethene is produced according to the following gas-phase synthesis:
2C (s) + 2H2 (g) → C2H4 (g)
Thermodynamic data for the components of this equilibrium are
Change
|
Value
|
ΔHϴr / kJ mol-1
|
p
|
ΔSϴ / J K-1 mol-1
|
q
|
The free energy change for this reaction at 298 K is:
ΔGϴ = format('truetype')%3Bfont-weight%3Anormal%3Bfont-style%3Anormal%3B%7D%3C%2Fstyle%3E%3C%2Fdefs%3E%3Cline%20stroke%3D%22%23000000%22%20stroke-linecap%3D%22square%22%20stroke-width%3D%221%22%20x1%3D%222.5%22%20x2%3D%2279.5%22%20y1%3D%2218.5%22%20y2%3D%2218.5%22%2F%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2241.5%22%20y%3D%2213%22%3Ep%3C%2Ftext%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2214.5%22%20y%3D%2243%22%3E298%3C%2Ftext%3E%3Ctext%20font-family%3D%22math13b8a614226a953a8cd9526fca6%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2234.5%22%20y%3D%2243%22%3E%26%23xD7%3B%3C%2Ftext%3E%3Cline%20stroke%3D%22%23000000%22%20stroke-linecap%3D%22square%22%20stroke-width%3D%221%22%20x1%3D%2243.5%22%20x2%3D%2276.5%22%20y1%3D%2238.5%22%20y2%3D%2238.5%22%2F%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2260.5%22%20y%3D%2233%22%3Eq%3C%2Ftext%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2259.5%22%20y%3D%2253%22%3E1000%3C%2Ftext%3E%3C%2Fsvg%3E)
ΔGϴ = p - 298 x 
ΔGϴ = format('truetype')%3Bfont-weight%3Anormal%3Bfont-style%3Anormal%3B%7D%3C%2Fstyle%3E%3C%2Fdefs%3E%3Cline%20stroke%3D%22%23000000%22%20stroke-linecap%3D%22square%22%20stroke-width%3D%221%22%20x1%3D%222.5%22%20x2%3D%2249.5%22%20y1%3D%2219.5%22%20y2%3D%2219.5%22%2F%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%227.5%22%20y%3D%2214%22%3Ep%3C%2Ftext%3E%3Ctext%20font-family%3D%22math13b8a614226a953a8cd9526fca6%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2218.5%22%20y%3D%2214%22%3E%26%23xD7%3B%3C%2Ftext%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2236.5%22%20y%3D%2214%22%3E298%3C%2Ftext%3E%3Ctext%20font-family%3D%22Arial%22%20font-size%3D%2214%22%20text-anchor%3D%22middle%22%20x%3D%2226.5%22%20y%3D%2234%22%3Eq%3C%2Ftext%3E%3C%2Fsvg%3E)
Which statements are correct for the following reaction?
CO(NH2)2 (aq) + H2O (l) → CO2 (g) + 2NH3 (g)
|
ΔHϴr = +119 kJ mol-1
ΔSϴ = +354.8 J K-1 mol-1
|
- The reaction will be feasible at high temperatures
- The reaction will never be feasible
- The reaction becomes more disordered
Which of the following equations is used when calculating the temperature, in Kelvin, at which a reaction becomes feasible if ΔHΘ = x and ΔSΘ = y.
T = 
T = 
The ΔGϴf values for the following substances are shown.
Substance
|
ΔGϴf (kJ mol-1)
|
NH3 (g)
|
-16.4
|
O2 (g)
|
0
|
H2O (g)
|
-228.6
|
NO (g)
|
87.6
|
Which of the following is the correct calculation to determine ΔGϴ?
4NH3 (g) + 5O2 (g) ⇌ 6H2O (g) + 4NO (g)
(-228.6 + 87.6) + (-16.4)
(-16.4 x 4) - [(-228.6 x 6) + (87.6 x 4)]
[-228.6 + (87.6 x 4)] - (-16.4 x 4)
[(-228.6 x 6) + (87.6 x 4)] - (-16.4 x 4)