The table below shows data for the and values for some acids and bases at 298 K.
Acid |
Ka |
Base |
pKb |
C5H6OH |
1.02 x 10-10 |
(C2H5)3N |
3.25 |
O2NC6H4OH |
7.08 x 10-8 |
C6H5NH2 |
9.13 |
Which two formulas represent the weakest acid and the weakest base in the table?
The ionisation constant of water, Kw , at 40 °C is 2.92 x 10-14. Which of the following statements is correct?
The ionisation of water is exothermic
The pH of water is lower at 40 °C than at 25 °C
The Kb value for a base is 8.0 x 10-4 at 298 K. What is the pKa value for the conjugate acid at this temperature?
The pKb value of HPO42- is 6.8. What is its conjugate acid and what is the Ka value?
|
Conjugate acid |
Ka |
A. |
H2PO4- |
7.2 |
B. |
H3PO4 |
7.2 |
C |
H3PO4 |
1.67 x 10-7 |
D. |
H2PO4- |
6.3 x 10-8 |
The strengths of four bases are:
- Phenylamine pKb = 9.13
- Ethylamine Kb = 4.46 x 10-4
- 3-Nitrophenol pKb = 8.36
- Ethanol Kb = 3.16 x 10-16
What is the order of increasing base strength?
Ethanol < phenylamine < 3-nitrophenol < ethylamine
Ethanol < 3-nitrophenol < phenylamine < ethylamine
Ethylamine < 3-nitrophenol < phenylamine < ethanol
Ethylamine < phenylamine < 3-nitrophenol < ethanol