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DP IB Chemistry: HL

Topic Questions

Home / IB / Chemistry: HL / DP / Topic Questions / 3. Periodicity / 3.2 Oxides, Group 1 & Group 17 / Structured Questions: Paper 2


3.2 Oxides, Group 1 & Group 17

Question 1a

Marks: 2
a)
An acid base reaction occurs for the reaction between solid potassium bromide and concentrated sulfuric acid. The equation for this is:

2H2SO4 (aq) + 2KBr (s) → K2SO4 (aq) + SO2 (g) + Br2 (g) + 2H2O (l)

In this reaction redox products are also formed. List all of the redox products produced from the reaction between solid potassium bromide and concentrated sulfuric acid and give observations for any products.

[2]

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    Question 1b

    Marks: 4
    b)

    Explain why the reaction between solid potassium iodide and concentrated sulfuric acid produces hydrogen sulfide whereas the reaction between solid potassium bromide, and concentrated sulfuric acid does not. 

    [4]

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      Key Concepts
      Halogens

      Question 1c

      Marks: 2
      c)
      Hydrogen halides, H-X, are formed from the reaction of hydrogen and a halogen, X2. In solution hydrogen fluoride is classed as a weak acid, whereas HCl is classed as a strong acid. Explain this difference.
      [2]
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        Question 2a

        Marks: 1
        a)
        Describe the trends in first ionisation energy and atomic radius as you move up Group 1. 
        [1]
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          Question 2b

          Marks: 2
          b)
          Explain the connection between first ionisation energy and atomic radius seen in the alkali metals.
          [2]
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            Question 2c

            Marks: 3
            c)

            Potassium reacts with water to form hydrogen gas. Using sections 1 and 2 of the data booklet, determine the volume, in cm3, of hydrogen gas that could theoretically be produced at 273 K and 1.01105 Pa when 0.0587 g of potassium reacts with excess water.

            [3]

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              Question 3a

              Marks: 3
              a)
              Write equations for the separate reactions of lithium oxide and carbon dioxide with excess water and differentiate between the solutions formed. 


              Lithium oxide
              ................

              Carbon dioxide.............

              Differentiation..............

              [3]

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                Question 3b

                Marks: 1
                b)
                Suggest why it is surprising that dinitrogen monoxide dissolves in water to give a neutral solution.
                [1]
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                  Question 3c

                  Marks: 1
                  c)

                  Calcium carbide reacts with water to form ethyne, C2H2, and one other product.

                  Estimate the pH of the resultant solution.

                  [1]

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                    Question 4a

                    Marks: 3
                    a)

                    Impurities cause phosphine to ignite spontaneously in the air to form an oxide of phosphorus and water.

                    The oxide formed in the reaction with air contains 56.3 % phosphorus by mass. Determine the empirical formula of the oxide, showing your method.

                    [3]

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                      Question 4b

                      Marks: 1
                      b)
                      The molar mass of the oxide is approximately 220 g mol−1. Determine the molecular formula of the oxide.
                      [1]
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                        Question 4c

                        Marks: 1
                        c)
                        State the equation for the reaction of this oxide of phosphorus with water.
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                          Question 4d

                          Marks: 1
                          d)
                          Predict how dissolving an oxide of phosphorus would affect the electrical conductivity of water.
                          [1]
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                            Key Concepts
                            Making predictions