0%

DP IB Chemistry: HL

Topic Questions

Home / IB / Chemistry: HL / DP / Topic Questions / 12. Atomic Structure (HL only) / 12.1 Electrons in Atoms / Structured Questions: Paper 2


12.1 Electrons in Atoms

Question 1a

Marks: 2
a)
The successive ionisation energies of an element, X, are shown below. The vertical axis plots log (ionisation energy) instead of ionisation energy to represent the data without an unreasonably long vertical axis.

q1_12-1_electrons-in-atoms-sq-medium_ib_hl

Identify element X and give its full electron configuration.

    Assess your score
      
    Key Concepts
    Deducing the Group

    Question 1b

    Marks: 3
    b)
    Explain how the successive ionisation energy data for the element X are related to its electron configuration.

      Assess your score
        

      Question 1c

      Marks: 2
      c)
      Explain why the first ionisation energy of aluminium is lower than the first ionisation energy of magnesium.

        Assess your score
          
        Key Concepts
        Trends Across a Period

        Question 1d

        Marks: 2
        d)
        Explain why the first ionisation energy of sulfur is lower than the first ionisation energy of phosphorus.
          Assess your score
            
          Key Concepts
          Trends Across a Period

          Question 2a

          Marks: 2
          a)
          The successive ionisation energies of vanadium are shown.

          q2a_12-1_electrons-in-atoms-sq-medium_ib_hl

          State the sub-levels from which each of the first four electrons are lost

            Assess your score
              

            Question 2b

            Marks: 2
            b)
            Outline why there is an increase in ionisation energy from electron 3 to electron 5.
              Assess your score
                

              Question 2c

              Marks: 3
              c)
              Explain why there is a large increase in the ionisation energy between electrons 5 and 6.
                Assess your score
                  

                Question 2d

                Marks: 2
                d)
                The first six ionisation energies, in kJ mol-1, of an element are shown below
                   

                IE1

                IE2

                IE3

                IE4

                IE5

                IE6

                578

                1816

                2744

                11576

                14829

                18375

                 

                Explain the large increase in ionisation energy from IE3 to IE4
                  Assess your score
                    

                  Question 3a

                  Marks: 2
                  a)
                  Emission spectra provide experimental evidence for the existence of atomic energy levels.

                  i)
                  Explain the convergence of lines in a hydrogen emission spectrum.

                  ii)
                  State what can be determined from the frequency of the convergence limit.

                    Assess your score
                      

                    Question 3b

                    Marks: 2
                    b)
                    Determine the energy, in J, of a photon of red light, correct to two significant figures, given that the wavelength is 650.0 nm using Sections 1 and 2 of the Data Booklet.
                      Assess your score
                        

                      Question 3c

                      Marks: 3
                      c)
                      Calculate the first ionisation energy, in kJ begin mathsize 16px style mol to the power of negative 1 end exponent end style, for hydrogen given that its shortest wavelength in the Lyman series is 91.16 nm using Sections 1 and 2 of the Data Booklet.
                        Assess your score
                          

                        Question 3d

                        Marks: 3
                        d)
                        Describe why the energy required to reach the convergence limit on an emission spectrum is considered the ionisation energy for an atom. You should refer to the appearance of the spectrum, frequency, and energy in your answer.
                          Assess your score
                            

                          Question 4a

                          Marks: 3
                          a)

                          The first ionisation energies of the elements in period 3 are shown below.

                          q4a_12-1_electrons-in-atoms-sq-medium_hb_hl

                          Explain the general trend seen in ionisation energy across period 3.

                            Assess your score
                              
                            Key Concepts
                            Trends Across a Period

                            Question 4b

                            Marks: 2
                            b)

                            On the diagram below, sketch the line for the first ionisation energies of period 2 elements

                            q4b_12-1_electrons-in-atoms-sq-medium_ib_hl

                              Assess your score
                                
                              Key Concepts
                              Trends Across a Period

                              Question 4c

                              Marks: 5
                              c)
                              Sketch a graph of ionisation energy versus the number of electrons removed for five ionisations of silicon. Explain the shape of the trend you have drawn.
                              q4c_12-1_electrons-in-atoms_ib_hl-medium
                                Assess your score
                                  

                                Question 4d

                                Marks: 2
                                d)
                                The wavelength of a line in the Balmer series of hydrogen is 726.2 m. Calculate the energy of photons emitted, in kJ, using Sections 1 and 2 of the Data Booklet.
                                  Assess your score
                                    

                                  Question 5a

                                  Marks: 2
                                  a)
                                  The first ionisation energies of the elements in period 3 are shown.

                                  q5a_12-1_electrons-in-atoms-sq-medium_ib_hl

                                  Draw a graph on the diagram to to show the second ionisation energies of the period 3 elements

                                    Assess your score
                                      
                                    Key Concepts
                                    Trends Across a Period

                                    Question 5b

                                    Marks: 3
                                    b)
                                    Explain the differences seen in first and second ionisation energies of the elements in period 3.
                                      Assess your score
                                        
                                      Key Concepts
                                      Trends Across a Period

                                      Question 5c

                                      Marks: 2
                                      c)

                                      Hydrogen spectral data give the frequency of 3.28 x 1015  s-1 for its convergence limit.

                                      i)
                                      Calculate the ionisation energy, in J, for a single atom of hydrogen using Sections 1 and 2 of the Data Booklet.

                                      ii)
                                      Calculate the wavelength, in nm, for the electron transition corresponding to the frequency in part (i) using Section 1 of the Data Booklet.
                                        Assess your score
                                          

                                        Question 5d

                                        Marks: 2
                                        d)
                                        On the diagram below, draw a line that corresponds to the first ionisation energy of hydrogen and explain your reasoning.

                                        q5d_12-1_electrons-in-atoms-sq-medium_ib_hl
                                          Assess your score