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Date May 2009 Marks available 4 Reference code 09M.3.sl.TZ1.A2
Level SL Paper 3 Time zone TZ1
Command term Distinguish Question number A2 Adapted from N/A

Question

Distinguish between the \(^{\text{1}}{\text{H}}\,{\text{NMR}}\) spectra of 1-bromopropane and 2-bromopropane (splitting patterns are not required).

Markscheme

2-bromopropane will show two separate absorptions/peaks;

in the ratio 6:1;

1-bromopropane will show three separate absorptions/peaks;

in the ratio 3:2:2;

Examiners report

In (a) most candidates correctly determined the difference in the number of peaks in the \(^{\text{1}}{\text{H}}\,{\text{NMR}}\) spectra of 1- bromopropane and 2 – bromopropane but neglected to mention or misinterpreted the differences in area under the peaks.

Syllabus sections

Core » Topic 11: Measurement and data processing » 11.3 Spectroscopic identification of organic compounds
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