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Date May 2013 Marks available 2 Reference code 13M.3.sl.TZ2.A3c
Level SL Paper 3 Time zone TZ2
Command term Explain Question number A3c Adapted from N/A

Question

Three isomers of \({{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}{{\text{O}}_{\text{2}}}\) are ethyl methanoate, methyl ethanoate and propanoic acid.

M13/4/CHEMI/SP3/ENG/TZ2/A3

Explain which of the three compounds has a \(^{\text{1}}{\text{H}}\,{\text{NMR}}\) spectrum showing two peaks with equal areas under each peak.

Markscheme

methyl ethanoate;

the only one with (the six H atoms in) two different chemical environments / the two CH3 groups give equal areas / OWTTE;

Award [1] for correct second marking point in (a)–(c) even if compound is wrongly identified.

Examiners report

Many students could use the spectroscopic data provided to correctly identify the compounds, with the first part of the question, dealing with mass spectrometer data, probably proving the most challenging.

Syllabus sections

Core » Topic 11: Measurement and data processing » 11.3 Spectroscopic identification of organic compounds
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