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Date May 2012 Marks available 6 Reference code 12M.2.hl.TZ2.4
Level HL Paper 2 Time zone TZ2
Command term Draw Question number 4 Adapted from N/A

Question

Draw the Lewis structures, predict the shape and deduce the bond angles for xenon tetrafluoride and the nitrate ion.

M12/4/CHEMI/HP2/ENG/TZ2/04

Markscheme

M12/4/CHEMI/HP2/ENG/TZ2/04/M

Accept any combination of lines, dots or crosses to represent electron pairs.

Examiners report

Many candidates had difficulties with the Lewis structure of the nitrate ion, putting too many electrons around the nitrogen atom or omitting the negative charge. They did better with XeF4, giving correct shape and bond angles. Some candidates lost marks for omitting lone pairs from the F atoms, and some had only 4 negative charge centres around Xe. Some teachers expressed concern that only exceptions to rules were being examined, but both \({\text{NO}}_3^ - \) and \({\text{Xe}}{{\text{F}}_{\text{4}}}\) are listed as examples to use in the teacher‘s notes.

Syllabus sections

Additional higher level (AHL) » Topic 14: Chemical bonding and structure » 14.1 Covalent bonding and electron domain and molecular geometries
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