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Date May 2009 Marks available 1 Reference code 09M.3.sl.TZ1.D3
Level SL Paper 3 Time zone TZ1
Command term Describe Question number D3 Adapted from N/A

Question

Ethanol is a depressant that is widely consumed in many societies. When consumed excessively it has a major impact on families and society as a whole. Other depressants such as diazepam (Valium®) may be prescribed by a doctor.

One problem associated with ethanol consumption is an increased risk of traffic accidents. Police in many countries use a breathalyser to test drivers. The breathalyser contains potassium dichromate(VI).

Describe the colour change of potassium dichromate(VI) when it reacts with ethanol.

[1]
b.i.

State with a reason whether chromium in potassium dichromate(VI) is oxidised or reduced by ethanol.

[1]
b.ii.

Markscheme

orange to green;

b.i.

reduced because oxidation number of Cr decreases / Cr gains electrons;

Explanation needed for mark.

b.ii.

Examiners report

[N/A]
b.i.

Candidates frequently confused oxidation and reduction or failed to provide a reason as to whether the chromium was oxidised or reduced by ethanol. This highlighted, again, the need for candidates to answer all parts of the question.

b.ii.

Syllabus sections

Core » Topic 10: Organic chemistry » 10.2 Functional group chemistry
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