0%

DP IB Chemistry: SL

Topic Questions

Home / IB / Chemistry: SL / DP / Topic Questions / 6. Chemical Kinetics / 6.1 Chemical Kinetics / Structured Questions: Paper 2


6.1 Chemical Kinetics

Question 1a

Marks: 2
a)
A group of students planned how to investigate the effect of changing the concentration of H2SO4 on the initial rate of reaction with magnesium:
 
Mg (s) + H2SO(aq) rightwards arrowMgSO4 (aq) + H2 (g)
 
They decided to measure how long the reaction took to complete when similar masses of magnesium were added to acid.
 
Two methods were suggested:
Method 1 - Use small pieces of magnesium ribbon, an excess of acid and record the time taken for the magnesium ribbon to disappear
Method 2 - Use large strips of magnesium ribbon, an excess of magnesium and record the time taken for bubbles to stop forming
 
Deduce, giving a reason, which of method 1 and method 2 would be the least affected if the masses of magnesium ribbon used varied slightly between each experiment.
[2]
    Assess your score
      
    Key Concepts
    Rate experiments

    Question 1b

    Marks: 2
    b)
    Neither method in part a) actually allows the initial rate to be calculated. Outline a method that would allow the calculation of initial rate.
    [2]
      Assess your score
        
      Key Concepts
      Rate experiments

      Question 1c

      Marks: 1
      c)
      The reaction is to be conducted across a few weeks.
      State a factor that has a significant effect on reaction rate, which could vary between experiments across the weeks and therefore needs to be controlled.
      [1]
        Assess your score
          
        Key Concepts
        Rate experiments

        Question 1d

        Marks: 4
        d)
        One group collected the following data using 1.50 mol dm-3 acid:
         
         
        Trial Time/ s (plus-or-minus 0.01 s)
        1 91.56
        2 98.33
        3 72.08
        4 89.41

        i)
        Comment on the use of the uncertainty when calculating the mean.
        [2]
        ii)
        Calculate the mean time for the set of results.
        [2]
          Assess your score
            

          Question 2a

          Marks: 5
          a)
          When investigating the reaction between sulfuric acid and calcium carbonate, it was observed that a small increase of temperature of around 10 oC caused a doubling in the rate of the reaction.
          Sketch and label Maxwell-Boltzmann curve for the two temperatures T and T+10, and use this diagram to help to explain this effect of temperature on rate.
          [5]
            Assess your score
              

            Question 2b

            Marks: 2
            b)
            Why do some collisions at high temperatures still not result in the formation of the product?
            [2]
              Assess your score
                
              Key Concepts
              Explaining rates

              Question 2c

              Marks: 3
              c)
              Identify and explain another factor that affects the number of particles present in a solution with sufficient energy to react.
              [3]
                Assess your score
                  
                Key Concepts
                Explaining rates

                Question 2d

                Marks: 2
                d)
                Some groups investigating the effect of temperature on rate stirred their reactions, some did not.
                Explain the effect of stirring upon the rate of the reaction.
                [2]
                  Assess your score
                    
                  Key Concepts
                  Explaining rates

                  Question 3a

                  Marks: 5
                  a)
                  0.5 g of magnesium reacts with 50 cm3 of 0.01 moldm-3 nitric acid. Magnesium is in excess.
                  A graph monitoring the volume of hydrogen gas produced is shown below:

                  6-1-ib-sl-sq-hard-q3a-rate-of-reaction-graph
                  i)
                  Calculate the mean rate of reaction over the first 15 seconds of the reaction
                  [1]
                  ii)
                  Calculate the actual rate of reaction at 15 seconds
                  [3]
                  iii)
                  Explain the difference in values for rate
                  [1]
                    Assess your score
                      

                    Question 3b

                    Marks: 3
                    b)
                    Compare the expected rate and progress of the reaction if 25 cm3 of 0.2 mol dm-3 nitric acid was used instead of 50 cm3 of 0.1 mol dm-3 nitric acid.
                    [3]
                      Assess your score
                        

                      Question 3c

                      Marks: 2
                      c)
                      Suggest one change to the reaction that could be made to produce more hydrogen gas in total and explain your choice.
                      [2]
                        Assess your score
                          
                        Key Concepts
                        Explaining rates

                        Question 3d

                        Marks: 2
                        d)
                        Suggest why it is often better to study a slower reaction instead of a faster one.
                        [2]
                          Assess your score
                            
                          Key Concepts
                          Rate experiments

                          Question 4a

                          Marks: 1
                          a)
                          The following energy profile diagram shows the pathways for both a catalysed and uncatalysed reversible reaction:
                          6-1-ib-sl-sq-hard-q4a-energy-profile-diagram
                          Identify the letter(s) representing the activation energy for the catalysed reverse reaction.
                          [1]
                            Assess your score
                              

                            Question 4b

                            Marks: 2
                            b)
                            State and explain the effect that this catalyst will have on the equilibrium yield.
                            [2]
                              Assess your score
                                
                              Key Concepts
                              How catalysts work

                              Question 4c

                              Marks: 2
                              c)
                              Vehicles with combustion engines usually have catalytic convertors added to catalyse the oxidation of carbon monoxide into carbon dioxide and to catalyse the reduction of nitrogen oxides to nitrogen. These catalysts are usually rhodium or platinum.

                              Leaded fuels were phased out as they were found to poison these catalysts, binding irreversibly to the metal surface.

                              Explain the problems for drivers of the catalysts being poisoned.
                              [2]
                                Assess your score
                                  
                                Key Concepts
                                How catalysts work

                                Question 4d

                                Marks: 1
                                d)
                                Suggest a situation in which using a catalyst would not be appropriate.
                                [1]
                                  Assess your score
                                    
                                  Key Concepts
                                  How catalysts work