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Date May 2009 Marks available 3 Reference code 09M.3.hl.TZ1.B2
Level HL Paper 3 Time zone TZ1
Command term Calculate Question number B2 Adapted from N/A

Question

Many lipids are found in the human body. One type of lipid is a triglyceride

To measure the degree of unsaturation of a lipid the iodine number can be calculated.

Calculate the iodine number of linoleic acid.

\[\begin{array}{*{20}{l}} {{\text{C}}{{\text{H}}_{\text{3}}}{{{\text{(C}}{{\text{H}}_{\text{2}}}{\text{)}}}_{\text{4}}}{{{\text{(CH=CHC}}{{\text{H}}_{\text{2}}}{\text{)}}}_{\text{2}}}{{{\text{(C}}{{\text{H}}_{\text{2}}}{\text{)}}}_{\text{6}}}{\text{COOH}}}&{{M_{\text{r}}} = 280.4} \end{array}\]

Markscheme

(amount of linoleic acid in 100 g =) \(\frac{{100}}{{280.4}} = 0.357{\text{ mol}}\);

2 double bonds in molecule so 1 mole of lipid reacts with 2 moles of \({{\text{I}}_{\text{2}}}\);

Can be implied in working.

mass of iodine that reacts \(( = 253.8 \times 0.357 \times 2) = 181{\text{ g}}\);

Award [3] for correct final answer.

Award [2] for 90.5 g.

Examiners report

In (b) many candidates could not define iodine number, with many referring to moles instead of grams. This then meant that few were able to calculate the iodine number successfully.

Syllabus sections

Options » B: Biochemistry » B.3 Lipids
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