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Date May 2015 Marks available 2 Reference code 15M.3.hl.TZ2.8
Level HL Paper 3 Time zone TZ2
Command term Calculate Question number 8 Adapted from N/A

Question

Linolenic acid (omega-3 fatty acid) is an essential fatty acid.

Calculate the iodine number for linolenic acid, \({{\text{C}}_{{\text{17}}}}{{\text{H}}_{{\text{29}}}}{\text{COOH (}}{{\text{M}}_{\text{r}}} = 278.48{\text{)}}\). The condensed structural formula of linolenic acid is given in table 22 of the data booklet.

Markscheme

\({{\text{n}}_{{\text{iodine}}}} = {\text{3}}{{\text{n}}_{{\text{linolenic acid}}}}\);

\({\text{iodine number }}\left( { = \frac{{3 \times 100 \times 253.8}}{{278.48}}} \right) = 273{\text{(g)}}\);

Award [2] for final correct answer.

If alternative definition, in terms of moles/C=C bonds is given, award [1 max] for iodine number = 3.

Examiners report

Quite a few candidates were aware of the benefits of linolenic acid, though identifying the number of carbon-carbon double bonds present, and using this to calculate the iodine number, was rather more challenging.

Syllabus sections

Options » B: Biochemistry » B.3 Lipids
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