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Date May 2010 Marks available 1 Reference code 10M.2.hl.TZ2.4
Level HL Paper 2 Time zone TZ2
Command term Comment Question number 4 Adapted from N/A

Question

One important property of a rocket fuel mixture is the large volume of gaseous products formed which provide thrust. Hydrazine, N2H4, is often used as a rocket fuel. The combustion of hydrazine is represented by the equation below.

\[\begin{array}{*{20}{l}} {{{\text{N}}_{\text{2}}}{{\text{H}}_{\text{4}}}{\text{(g)}} + {{\text{O}}_{\text{2}}}({\text{g)}} \to {{\text{N}}_{\text{2}}}({\text{g)}} + 2{{\text{H}}_{\text{2}}}{\text{O(g)}}}&{\Delta H_{\text{c}}^\Theta = - {\text{585 kJ}}\,{\text{mo}}{{\text{l}}^{ - 1}}} \end{array}\]

Comment on the environmental safety of the products of the reaction of \({{\text{N}}_{\text{2}}}{{\text{H}}_{\text{4}}}\) with \({{\text{O}}_{\text{2}}}\) and the reaction of \({{\text{N}}_{\text{2}}}{{\text{H}}_{\text{4}}}\) with \({{\text{F}}_{\text{2}}}\).

Markscheme

(\({{\text{N}}_{\text{2}}}\) inert) HF (weak) acid compared to \({{\text{H}}_2}{\text{O}}\) / HF toxic / products of reactions of HF with environment/soil are harmful to environment / OWTTE;

Examiners report

A matter of serious concern is the number of candidates who identified nitrogen as harmful to the environment or a greenhouse gas.

Syllabus sections

Core » Topic 5: Energetics/thermochemistry » 5.3 Bond enthalpies
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