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Date May 2015 Marks available 1 Reference code 15M.1.sl.TZ2.16
Level SL Paper 1 Time zone TZ2
Command term Question number 16 Adapted from N/A

Question

Which enthalpy changes can be calculated using only bond enthalpy data?

I.     \({{\text{N}}_{\text{2}}}{\text{(g)}} + {\text{3}}{{\text{H}}_{\text{2}}}{\text{(g)}} \to {\text{2N}}{{\text{H}}_{\text{3}}}{\text{(g)}}\)

II.     \({{\text{C}}_{\text{2}}}{{\text{H}}_{\text{5}}}{\text{OH(l)}} + {\text{3}}{{\text{O}}_{\text{2}}}{\text{(g)}} \to {\text{2C}}{{\text{O}}_{\text{2}}}{\text{(g)}} + {\text{3}}{{\text{H}}_{\text{2}}}{\text{O(g)}}\)

III.     \({\text{C}}{{\text{H}}_{\text{4}}}{\text{(g)}} + {\text{C}}{{\text{l}}_{\text{2}}}{\text{(g)}} \to {\text{C}}{{\text{H}}_{\text{3}}}{\text{Cl(g)}} + {\text{HCl(g)}}\)

A.     I and II only

B.     I and III only

C.     II and III only

D.     I, II and III

Markscheme

B

Examiners report

It should have been clear to candidates that liquid ethanol would require more than bond enthalpy data provided they knew the definition of the latter. 52% gave the correct answer. 

Syllabus sections

Core » Topic 5: Energetics/thermochemistry » 5.3 Bond enthalpies
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