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Date May 2013 Marks available 2 Reference code 13M.3.sl.TZ1.B2
Level SL Paper 3 Time zone TZ1
Command term Draw Question number B2 Adapted from N/A

Question

Monosaccharides and disaccharides are classes of carbohydrates.

Describe the structural features of monosaccharides.

[2]
a.

Draw the structures of \(\alpha \)-glucose and \(\beta \)-glucose.

 

\[\alpha {\text{ - glucose}}\quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \quad \beta {\text{ - glucose}}\]

[2]
b.i.

Two \(\alpha \)-glucose molecules condense to form the disaccharide maltose. Draw the structure of maltose.

[1]
b.ii.

Markscheme

contain carbonyl (group)/C=O;

have at least two hydroxyl/OH (groups);

Do not accept hydroxide instead of hydroxyl.

\({\text{C}}{{\text{H}}_{\text{2}}}{\text{O}}\) empirical formula;

Do not accept CxH2yOy or C6H12O6.

a.

M13/4/CHEMI/SP3/ENG/TZ1/B2.b.i/M

Award [1 max] if position of OH is correct in both structures at C1 but other groups/moieties (eg, CH2OH) or H are missing.

Award [1 max] if the alpha and beta structures are labelled in reverse.

b.i.

M13/4/CHEMI/SP3/ENG/TZ1/B2.b.ii/M

b.ii.

Examiners report

Only some of the candidates described a monosaccharide correctly in part (a) although its features are given in the programme guide. Drawing alpha and beta glucose was also a discriminating question.

a.

About a third of candidates were able to score full marks on part (b)(i).

b.i.

Similarly, drawing maltose in part (d)(ii) was a challenge for the majority of candidates. Many had missing hydrogen atoms or an incorrect orientation of bonds around the linkage.

b.ii.

Syllabus sections

Options » B: Biochemistry » B.10 Stereochemistry in biomolecules (HL only)
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