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Date May 2011 Marks available 1 Reference code 11M.3.hl.TZ1.F4
Level HL Paper 3 Time zone TZ1
Command term Comment Question number F4 Adapted from N/A

Question

The stereochemistry of molecules affects the way they interact with taste and smell receptors in the body.

The stereochemistry of carbohydrates and amino acids is usually indicated by the D/L convention.

Alanine has the formula \({\text{[}}{{\text{H}}_{\text{2}}}{\text{N}}–{\text{CH(C}}{{\text{H}}_{\text{3}}}{\text{)}}–{\text{COOH]}}\). Deduce the structure of D-alanine and complete its structure below.

[1]
b.i.

State which convention is usually employed to indicate the stereochemistry of molecules other than carbohydrates and amino acids.

[1]
b.ii.

Based on the structure given in part (b) (i) comment on the statement “D-alanine is a +(d) compound”.

[1]
b.iii.

Markscheme

M11/4/CHEMI/HP3/ENG/TZ1/G4.b.i/M

b.i.

the R– S– convention;

b.ii.

not possible to tell;

b.iii.

Examiners report

This was a low scoring question, particularly parts (b) (ii) and (b) (iii).

b.i.

This was a low scoring question, particularly parts (b) (ii) and (b) (iii).

b.ii.

This was a low scoring question, particularly parts (b) (ii) and (b) (iii).

b.iii.

Syllabus sections

Options » B: Biochemistry » B.10 Stereochemistry in biomolecules (HL only)
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