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Date November 2013 Marks available 2 Reference code 13N.3.hl.TZ0.12
Level HL Paper 3 Time zone TZ0
Command term Suggest Question number 12 Adapted from N/A

Question

Chemistry has made a significant contribution to the development of liquid-crystal displays (LCDs).

The diagram below is a representation of an LCD. The planes of polarization of the analyser and the polarizer are at right angles to each other.

N13/4/CHEMI/HP3/ENG/TZ0/12

State what the observer would see if the liquid crystal was not present and there was no voltage between the electrodes \({{\text{E}}_{\text{1}}}\) and \({{\text{E}}_{\text{2}}}\).

[1]
a.

Explain how the addition of a liquid crystal to the cell changes what the observer sees.

[2]
b.i.

Explain how the application of an electric field between the electrodes, \({{\text{E}}_{\text{1}}}\) and \({{\text{E}}_{\text{2}}}\), changes what the observer sees in b (i).

[2]
b.ii.

The molecule below has liquid-crystal display properties.

N13/4/CHEMI/HP3/ENG/TZ0/12.c

Suggest two reasons why the molecule is suitable for use in liquid-crystal display devices.

[2]
c.

Markscheme

nothing / whole area black;

Accept no light transmitted.

a.

the molecules form a twisted arrangement;

liquid crystal rotates the plane of polarization (so light is now transmitted by the analyser);

b.i.

(with electric field) the molecules are aligned/not twisted;

so light is not transmitted;

b.ii.

rod shape / rigid;

chemically stable (due to hydrocarbon rings and chain);

polar (due to the presence of F) / OWTTE;

can change orientation / rapid switching in electric field/when voltage is applied;

c.

Examiners report

Option C was not a popular option.

While many candidates scored the mark in 10 (a), those who did not often failed to provide the correct name for an ore. Although many identified slag, some were able to give the correct equation and others gave equations which were either incorrect or not from raw materials as asked. This question unfortunately shows that chemical equations seem not to be as well covered as expected. The answer to the question on alloys was rather disappointing and weaker than in previous sessions. The lack of subject specific vocabulary was often observed with many candidates providing answers that were clearly not addressing the question. Very few candidates were able to score even one mark on the mechanism by which the carbon chain increases in length during the manufacture of LDPE suggesting that this topic requires further attention. Many candidates were familiar with the catalyst used in the formation of HDPE although some lost the mark due to writing names that differed widely from correct one. Many were able to score at least one mark for the structure of the isotactic form of the polymer but very few drew 3D structures. Many candidates were able to score partial points when explaining why the isotactic form is more suitable for the manufacture of strong fibres but many missed the idea of chains not being able to move past each other easily (hence fibre is strong/rigid).

The part on liquid crystal displays was done with mixed results with many correct answers but still below expectations. Many candidates scored a mark for the explanation of how the addition of a LC to a cell changes what the observer sees usually from establishing the rotation of the plane of polarized light, but far too often replies were shallow with limited use of correct terminology. In the explanation of how the application of an electric filed between electrodes changes what the observer sees, many students were able to score one mark by stating that light is not transmitted but only stronger candidates included in their answers that molecules are aligned or not twisted. The question on the Ni-Cd battery was answered poorly with many candidates not even attempting it or getting the equation completely wrong and not being able to identify insolubility of the products that allows the reaction to be reversed and the cell charged. Description of the addition of small amounts of arsenic to increase the conductivity of silicon was surprising not done well and is a topic that needs closer attention.

a.

Option C was not a popular option.

While many candidates scored the mark in 10 (a), those who did not often failed to provide the correct name for an ore. Although many identified slag, some were able to give the correct equation and others gave equations which were either incorrect or not from raw materials as asked. This question unfortunately shows that chemical equations seem not to be as well covered as expected. The answer to the question on alloys was rather disappointing and weaker than in previous sessions. The lack of subject specific vocabulary was often observed with many candidates providing answers that were clearly not addressing the question. Very few candidates were able to score even one mark on the mechanism by which the carbon chain increases in length during the manufacture of LDPE suggesting that this topic requires further attention. Many candidates were familiar with the catalyst used in the formation of HDPE although some lost the mark due to writing names that differed widely from correct one. Many were able to score at least one mark for the structure of the isotactic form of the polymer but very few drew 3D structures. Many candidates were able to score partial points when explaining why the isotactic form is more suitable for the manufacture of strong fibres but many missed the idea of chains not being able to move past each other easily (hence fibre is strong/rigid).

The part on liquid crystal displays was done with mixed results with many correct answers but still below expectations. Many candidates scored a mark for the explanation of how the addition of a LC to a cell changes what the observer sees usually from establishing the rotation of the plane of polarized light, but far too often replies were shallow with limited use of correct terminology. In the explanation of how the application of an electric filed between electrodes changes what the observer sees, many students were able to score one mark by stating that light is not transmitted but only stronger candidates included in their answers that molecules are aligned or not twisted. The question on the Ni-Cd battery was answered poorly with many candidates not even attempting it or getting the equation completely wrong and not being able to identify insolubility of the products that allows the reaction to be reversed and the cell charged. Description of the addition of small amounts of arsenic to increase the conductivity of silicon was surprising not done well and is a topic that needs closer attention.

b.i.

Option C was not a popular option.

While many candidates scored the mark in 10 (a), those who did not often failed to provide the correct name for an ore. Although many identified slag, some were able to give the correct equation and others gave equations which were either incorrect or not from raw materials as asked. This question unfortunately shows that chemical equations seem not to be as well covered as expected. The answer to the question on alloys was rather disappointing and weaker than in previous sessions. The lack of subject specific vocabulary was often observed with many candidates providing answers that were clearly not addressing the question. Very few candidates were able to score even one mark on the mechanism by which the carbon chain increases in length during the manufacture of LDPE suggesting that this topic requires further attention. Many candidates were familiar with the catalyst used in the formation of HDPE although some lost the mark due to writing names that differed widely from correct one. Many were able to score at least one mark for the structure of the isotactic form of the polymer but very few drew 3D structures. Many candidates were able to score partial points when explaining why the isotactic form is more suitable for the manufacture of strong fibres but many missed the idea of chains not being able to move past each other easily (hence fibre is strong/rigid).

The part on liquid crystal displays was done with mixed results with many correct answers but still below expectations. Many candidates scored a mark for the explanation of how the addition of a LC to a cell changes what the observer sees usually from establishing the rotation of the plane of polarized light, but far too often replies were shallow with limited use of correct terminology. In the explanation of how the application of an electric filed between electrodes changes what the observer sees, many students were able to score one mark by stating that light is not transmitted but only stronger candidates included in their answers that molecules are aligned or not twisted. The question on the Ni-Cd battery was answered poorly with many candidates not even attempting it or getting the equation completely wrong and not being able to identify insolubility of the products that allows the reaction to be reversed and the cell charged. Description of the addition of small amounts of arsenic to increase the conductivity of silicon was surprising not done well and is a topic that needs closer attention.

b.ii.

Option C was not a popular option.

While many candidates scored the mark in 10 (a), those who did not often failed to provide the correct name for an ore. Although many identified slag, some were able to give the correct equation and others gave equations which were either incorrect or not from raw materials as asked. This question unfortunately shows that chemical equations seem not to be as well covered as expected. The answer to the question on alloys was rather disappointing and weaker than in previous sessions. The lack of subject specific vocabulary was often observed with many candidates providing answers that were clearly not addressing the question. Very few candidates were able to score even one mark on the mechanism by which the carbon chain increases in length during the manufacture of LDPE suggesting that this topic requires further attention. Many candidates were familiar with the catalyst used in the formation of HDPE although some lost the mark due to writing names that differed widely from correct one. Many were able to score at least one mark for the structure of the isotactic form of the polymer but very few drew 3D structures. Many candidates were able to score partial points when explaining why the isotactic form is more suitable for the manufacture of strong fibres but many missed the idea of chains not being able to move past each other easily (hence fibre is strong/rigid).

The part on liquid crystal displays was done with mixed results with many correct answers but still below expectations. Many candidates scored a mark for the explanation of how the addition of a LC to a cell changes what the observer sees usually from establishing the rotation of the plane of polarized light, but far too often replies were shallow with limited use of correct terminology. In the explanation of how the application of an electric filed between electrodes changes what the observer sees, many students were able to score one mark by stating that light is not transmitted but only stronger candidates included in their answers that molecules are aligned or not twisted. The question on the Ni-Cd battery was answered poorly with many candidates not even attempting it or getting the equation completely wrong and not being able to identify insolubility of the products that allows the reaction to be reversed and the cell charged. Description of the addition of small amounts of arsenic to increase the conductivity of silicon was surprising not done well and is a topic that needs closer attention.

c.

Syllabus sections

Options » A: Materials » A.4 Liquid crystals
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