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Date November 2013 Marks available 1 Reference code 13N.1.hl.TZ0.28
Level HL Paper 1 Time zone TZ0
Command term Deduce Question number 28 Adapted from N/A

Question

The table below shows data for the \({{K_{\text{a}}}}\) and \({{\text{p}}{K_{\text{b}}}}\) values for some acids and bases at 298 K.

N13/4/CHEMI/HPM/ENG/TZ0/28

Which two formulas represent the weakest acid and the weakest base in the table?

A.     HClO and \({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)

B.     \({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) and \({\text{N}}{{\text{H}}_{\text{3}}}\)

C.     \({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{C}}{{\text{H}}_{\text{2}}}{\text{COOH}}\) and \({{\text{C}}_{\text{6}}}{{\text{H}}_{\text{5}}}{\text{N}}{{\text{H}}_{\text{2}}}\)

D.     HClO and \({\text{N}}{{\text{H}}_{\text{3}}}\)

Markscheme

A

Examiners report

It was thought “good to mix the data types, \({{\text{p}}{K_{\text{a}}}}\) and \({{K_{\text{a}}}}\)”. This was the fifth hardest question (60.81% correct) with the wrong answers almost equally chosen.

Syllabus sections

Additional higher level (AHL) » Topic 18: Acids and bases » 18.2 Calculations involving acids and bases
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