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Date November 2014 Marks available 1 Reference code 14N.1.hl.TZ0.27
Level HL Paper 1 Time zone TZ0
Command term Question number 27 Adapted from N/A

Question

Methylamine acts as a weak base when it reacts with water. For a diluted aqueous solution, what is the \({K_{\text{b}}}\) expression for this reaction?

A.     \({K_{\text{b}}} = \frac{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{NH}}_{\text{3}}^ + {\text{][O}}{{\text{H}}^ - }{\text{]}}}}{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{N}}{{\text{H}}_{\text{2}}}{\text{]}}}}\)

B.     \({K_{\text{b}}} = \frac{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{N}}{{\text{H}}_{\text{2}}}{\text{][}}{{\text{H}}_{\text{2}}}{\text{O]}}}}{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{NH}}_{\text{3}}^ + {\text{][O}}{{\text{H}}^ - }{\text{]}}}}\)

C.     \({K_{\text{b}}} = \frac{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{NH}}_{\text{3}}^ + {\text{][O}}{{\text{H}}^ - }{\text{]}}}}{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{N}}{{\text{H}}_{\text{2}}}{\text{][}}{{\text{H}}_{\text{2}}}{\text{O]}}}}\)

D.     \({K_{\text{b}}} = \frac{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{N}}{{\text{H}}_{\text{2}}}{\text{]}}}}{{{\text{[C}}{{\text{H}}_{\text{3}}}{\text{NH}}_{\text{3}}^ + {\text{][O}}{{\text{H}}^ - }{\text{]}}}}\)

Markscheme

A

Examiners report

Quite a few candidates included water in the expression, giving answer C.

Syllabus sections

Additional higher level (AHL) » Topic 18: Acids and bases » 18.2 Calculations involving acids and bases
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