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Date May 2016 Marks available 2 Reference code 16M.3.sl.TZ0.10
Level SL Paper 3 Time zone TZ0
Command term Calculate Question number 10 Adapted from N/A

Question

Glucose, C6H12O6, is a monosaccharide that our body can use as a source of energy.

Deduce the equation for the cellular respiration of glucose.

[1]
a.

Calculate the energy, in kJ, produced from 15.0g of glucose if its enthalpy of combustion is −2803kJmol−1.

[2]
b.

Glucose is the basic building block of starch which can be used to make bioplastics. Outline two advantages and two disadvantages of biodegradable plastics.

Two advantages:

 

Two disadvantages:
 
 

[4]
c.

Bioplastics are broken down by enzyme catalysed reactions. Sketch a graph illustrating how the rate of this reaction varies with pH.

[1]
d.

Markscheme

C6H12O6 (aq) + 6O2 (aq) → 6CO2 (aq) + 6H2O (l)

Accept equations for anaerobic respiration, such as C6H12O6 (aq) → 2C3H6O3 (aq)
Ignore ATP if added as a product.

 

a.

\(n\left( {{{\rm{C}}_{\rm{6}}}{{\rm{H}}_{{\rm{12}}}}{{\rm{O}}_{\rm{6}}}} \right)\left\langle { = \frac{{15.0}}{{180.18}}} \right\rangle  = 0.0833 \ll {\rm{mol}} \gg \)

«energy=0.0833×2803=»233«kJ»

Award [2] for correct final answer.
Accept -233«kJ».

b.

Two advantages:   
renewable resource
broken down/digested by bacteria or other organisms within a relatively short time/quickly
reduce «volume of» plastic waste/landfill

reduce use of petrochemicals
OR
reduce use of fossil fuels as hydrocarbon source

degrade into non-toxic products

Any two advantages for [2 max].
M2: reference must be made to time. Do not accept “biodegradable” (since stated in question).
Ignore any mention of cost.

Two disadvantages:
require use of land «for crop production»

increased use of fertilizers/pesticides «leading to pollution»
OR
eutrophication

might break down before end of use
release of methane/CH4/greenhouse gas «during degradation»

Any two disadvantages for [2 max].
Ignore any mention of cost.

c.

typical curve as shown in example above

Accept any curve with a single maximum (not just bell-shaped).
Ignore features such as pH values on a pH scale or a pH value at maximum (if given).
Do not penalize if curve does not touch the x-axis.

 

 

 

d.

Examiners report

[N/A]
a.
[N/A]
b.
[N/A]
c.
[N/A]
d.

Syllabus sections

Core » Topic 5: Energetics/thermochemistry » 5.1 Measuring energy changes
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