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Date May 2010 Marks available 2 Reference code 10M.3.hl.TZ1.C2
Level HL Paper 3 Time zone TZ1
Command term Write Question number C2 Adapted from N/A

Question

Kevlar can be made by reacting 1,4-diaminobenzene, \({{\text{H}}_{\text{2}}}{\text{N}}{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{4}}}{\text{N}}{{\text{H}}_{\text{2}}}\), with 1,4-benzenedicarbonyl chloride, \({\text{ClOC}}{{\text{C}}_{\text{6}}}{{\text{H}}_{\text{4}}}{\text{COCl}}\). Write the equation for the reaction of n molecules of 1,4-diaminobenzene reacting with n molecules of 1,4-benzenedicarbonyl chloride.

[2]
d.

Kevlar is an example of a lyotropic liquid crystal. Outline what is meant by lyotropic liquid crystal.

[2]
e.

Markscheme

M10/4/CHEMI/HP3/ENG/TZ1/C2.d/M

correct products;

correctly balanced;

d.

liquid crystals:

fluids with properties that depend on the molecular orientation relative to a fixed axis;

lyotropic:

solutions that show the liquid-crystal state at certain concentrations;

e.

Examiners report

Few candidates could give the correct equation to produce Kevlar, though some scored 1 mark for giving the correct products.

d.

The concept of liquid crystals was not understood by many. Very few mentioned that lyotropic is a solution.

e.

Syllabus sections

Options » A: Materials » A.9 Condensation polymers (HL only)
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