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Date May 2011 Marks available 2 Reference code 11M.2.hl.TZ1.1
Level HL Paper 2 Time zone TZ1
Command term Determine Question number 1 Adapted from N/A

Question

Methanol is made in large quantities as it is used in the production of polymers and in fuels. The enthalpy of combustion of methanol can be determined theoretically or experimentally.

CH3OH(l)+112O2(g)CO2(g)+2H2O(g)

M11/4/CHEMI/HP2/ENG/TZ1/01

Determine the ΔSΘ for the combustion of methanol.

CH3OH(l)+112O2(g)CO2(g)+2H2O(g)

[2]
d.

Using the enthalpy of combustion for methanol from Table 12 of the Data Booklet and the ΔSΘ determined in part (d), calculate the standard free energy change for the combustion of methanol.

[3]
e.

Explain whether changing the temperature will alter the spontaneity of the reaction.

[1]
f.

Markscheme

ΔSΘ(=SΘproductsSΘreactants)=2×189+214(240+1.5×205);

=44.5 JK1mol1/0.0445 kJK1mol1

Award [2] for correct final answer.

Do not award M2 if M1 incorrect.

d.

temperature of 298 K;

ΔGΘc=(ΔHΘcTΔSΘc=)726298×44.5×103 (kJmol1)/

=726000298×44.5 (Jmol1);

=739 kJmol1/7.39×105 Jmol1;

Award [3] for correct final answer.

e.

ΔGΘc is always negative and temperature won’t alter spontaneity of reaction;

f.

Examiners report

(d) caused difficulties for candidates with the multiplication factor for the oxygen and the correct units were frequently omitted which caused problems then subsequently in part (e).

d.

In (e), problems of units were widespread.

e.

(f) usually was well done by the better candidates. One G2 comment also stated that it would have been better if the experimental value would have been closer to the expected value.

f.

Syllabus sections

Additional higher level (AHL) » Topic 15: Energetics/thermochemistry » 15.2 Entropy and spontaneity
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