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Date May 2018 Marks available 1 Reference code 18M.3.hl.TZ1.4
Level HL Paper 3 Time zone TZ1
Command term Justify and Deduce Question number 4 Adapted from N/A

Question

Both HDPE (high density polyethene) and LDPE (low density polyethene) are produced by the polymerization of ethene.

An alternative method of polymerizing molecules is condensation polymerization. One of the earliest condensation polymers was nylon-6. A short section of the polymer chain of nylon-6 is shown below.

M18/4/CHEMI/HP3/ENG/TZ1/04.c

Draw the structure of the monomer from which nylon-6 is produced by a condensation reaction.

 

[2]
c.i.

Deduce, giving a reason, whether the atom economy of a condensation polymerization, such as this, would be greater or less than an addition polymerization, such as the formation of HDPE.

[1]
c.ii.

Markscheme

M18/4/CHEMI/HP3/ENG/TZ1/04.c.i/M

–NH2 AND –COOH

six C-atoms

 

Accept –COCl instead of –COOH.

[2 marks]

c.i.

less AND a second molecule/product formed

 

Accept “not all the reactant molecules «in the equation» are converted «to product molecules»”.

[1 mark]

c.ii.

Examiners report

[N/A]
c.i.
[N/A]
c.ii.

Syllabus sections

Options » A: Materials » A.5 Polymers
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