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Date May 2011 Marks available 2 Reference code 11M.3.hl.TZ1.A2
Level HL Paper 3 Time zone TZ1
Command term State and explain Question number A2 Adapted from N/A

Question

The \(^{\text{1}}{\text{H}}\,{\text{NMR}}\) spectrum of X with molecular formula \({{\text{C}}_{\text{3}}}{{\text{H}}_{\text{6}}}{\text{O}}\) is shown below.

M11/4/CHEMI/HP3/ENG/TZ1/A2

State and explain the splitting pattern you would expect in a high resolution spectrum for the peak at 1.1 ppm.

Markscheme

triplet;

next to a carbon atom that is attached to two hydrogen atoms;

Apply ECF.

CH3COCH3: singlet; no neighbouring H–atoms

CH2=CH–CH2OH: correct multiplicity and explanation for any peak.

Examiners report

Candidates understood this area well and scored most of the marks.

Syllabus sections

Additional higher level (AHL) » Topic 12: Atomic structure » 12.1 Electrons in atoms
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