State the factor that limits the maximum current that can be drawn from this cell and how electrodes are designed to maximize the current.

Deduce half-equations for the reactions at the two electrodes and hence the equation for the overall reaction.

Complete the half-equations on the diagram and identify the species moving between the electrodes.

Suggest a way in which they are similar.

A concentration cell is an example of an electrochemical cell.

(i) State the difference between a concentration cell and a standard voltaic cell.

(ii) The overall redox equation and the standard cell potential for a voltaic cell are:

Zn (s) + Cu²⁺ (aq) → Zn²⁺ (aq) + Cu (s)     E^θ_cell = +1.10 V

Determine the cell potential E at 298 K to three significant figures given the following concentrations in mol dm⁻³:

[Zn²⁺] = 1.00 × 10⁻⁴       [Cu²⁺] = 1.00 × 10⁻¹

Use sections 1 and 2 of the data booklet.

(iii) Deduce, giving your reason, whether the reaction in (b) (ii) is more or less spontaneous than in the standard cell.

Outline the function of the proton-exchange membrane (PEM) in the fuel cell.

Outline the difference between primary and rechargeable cells.

Identify one factor that affects the voltage of a cell and a different factor that affects the current it can deliver.

Deduce the half-equations and the overall equation for the reactions taking place in a direct methanol fuel cell (DMFC) under acidic conditions.

Outline why aqueous ethanol, rather than pure ethanol, is used in a DEFC.

Calculate the cell potential, E^θ, in V, using section 24 of the data booklet.

Suggest how PEM fuel cells can be used to produce a larger voltage than that calculated in (b)(i).

A voltaic cell consists of a nickel electrode in 1.0 mol dm⁻³ Ni²⁺ (aq) solution and a cadmium electrode in a Cd²⁺ (aq) solution of unknown concentration.

Cd (s) + Ni²⁺ (aq) → Cd²⁺ (aq) + Ni (s)               E^Θ_cell = 0.14 V

Determine the concentration of the Cd²⁺ (aq) solution if the cell voltage, E, is 0.19 V at 298 K. Use section 1 of the data booklet.

Outline how a microbial fuel cell produces an electric current from glucose.

C₆H₁₂O₆ (aq) + 6O₂ (g) → 6CO₂ (g) + 6H₂O (l)

The cell potential for the spontaneous reaction when standard magnesium and silver half-cells are connected is +3.17 V.

Determine the cell potential at 298 K when:

     [Mg²⁺] = 0.0500 mol dm⁻³
     [Ag⁺] = 0.100 mol dm⁻³

Use sections 1 and 2 of the data booklet.

Formulate half-equations for the reactions at the anode (negative electrode) and cathode (positive electrode) during discharge of a lithium-ion battery.

State the name and function of X in the diagram in (b)(i).

Name:

Function:

Explain how the flow of ions allows for the operation of the fuel cell.

Ethanol can be used in a direct-ethanol fuel cell (DEFC) as illustrated by the flow chart.

Deduce the half-equations occurring at electrodes A and B.

Electrode A: 

Electrode B:

The Geobacter species of bacteria can be used in microbial fuel cells to oxidise aqueous ethanoate ions,
CH₃COO⁻(aq), to carbon dioxide gas.

State the half-equations for the reactions at both electrodes.

Outline one advantage and one disadvantage of the methanol cell (DMFC) compared with a hydrogen-oxygen fuel cell.

Deduce the half-equations for the reactions occurring at the electrodes.

Anode (negative electrode):

Cathode (positive electrode):

Fuel cells have a higher thermodynamic efficiency than octane. The following table gives some information on a direct methanol fuel cell.

Determine the thermodynamic efficiency of a methanol fuel cell operating at 0.576 V.

Use sections 1 and 2 of the data booklet.