Date | November 2013 | Marks available | 1 | Reference code | 13N.2.hl.TZ0.2 |
Level | HL | Paper | 2 | Time zone | TZ0 |
Command term | Deduce | Question number | 2 | Adapted from | N/A |
Question
Consider the two-stage reaction pathway below.
Deduce the structural formula of compound X.
State the reagents and conditions required for stage II of the pathway.
Reagents:
Conditions:
Markscheme
;
Accept left hand end written as CH2(OH)–.
Reagents: acidified/H\(^ + \) dichromate ion/\({\text{C}}{{\text{r}}_{\text{2}}}{\text{O}}_7^{2 - }\)/potassium dichromate/\({{\text{K}}_{\text{2}}}{\text{C}}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\)/sodium dichromate/\({\text{N}}{{\text{a}}_{\text{2}}}{\text{C}}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}\);
Accept acidified/H+ permanganate ion/MnO4–/potassium permanganate/KMnO4.
Conditions: reflux;
Accept “heat” (as the intermediate aldehyde will not be volatile enough to vaporize significantly) unless distillation mentioned.
Examiners report
This was frequently well answered with many students gaining good marks. A common mistake was for students to identify the bond present in the polymer rather than the type of polymerization.
This was frequently well answered with many students gaining good marks. A common mistake was for students to identify the bond present in the polymer rather than the type of polymerization.