Date | May 2017 | Marks available | 3 | Reference code | 17M.3.hl.TZ2.4 |
Level | HL | Paper | 3 | Time zone | TZ2 |
Command term | Explain | Question number | 4 | Adapted from | N/A |
Question
EDTA is produced by reacting ethane-1,2-diamine with chloroethanoic acid, ClCH2COOH.
Identify the other product formed.
Explain why EDTA, a chelating agent, is more effective in removing heavy metal ions from solution than monodentate ligands.
Markscheme
HCl/hydrogen chloride
Accept “hydrochloric acid”.
[1 mark]
forms four/six/several/multiple coordinate/coordination bonds «to a central metal ion»
OR
is a polydentate/tetradentate/hexadentate ligand
forms more stable complex/stronger bonds with central metal ion
OR
increases entropy/S by releasing smaller «monodentate ligand» molecules previously complexed
complex ions are much larger «and can be removed easily due to large size of chelate complexes»
OR
heavy metal ions trapped inside the ligand/become «biologically» inactive/nontoxic/harmless
Accept “dative «covalent»” for “coordinate/coordination”.
Do not accept just “chelates”.
[3 marks]