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Date May 2017 Marks available 3 Reference code 17M.3.hl.TZ2.4
Level HL Paper 3 Time zone TZ2
Command term Explain Question number 4 Adapted from N/A

Question

EDTA is produced by reacting ethane-1,2-diamine with chloroethanoic acid, ClCH2COOH.

Identify the other product formed.

[1]
a.

Explain why EDTA, a chelating agent, is more effective in removing heavy metal ions from solution than monodentate ligands.

[3]
b.

Markscheme

HCl/hydrogen chloride

 

Accept “hydrochloric acid”.

[1 mark]

a.

forms four/six/several/multiple coordinate/coordination bonds «to a central metal ion»
OR
is a polydentate/tetradentate/hexadentate ligand

forms more stable complex/stronger bonds with central metal ion
OR
increases entropy/S by releasing smaller «monodentate ligand» molecules previously complexed

complex ions are much larger «and can be removed easily due to large size of chelate complexes»
OR
heavy metal ions trapped inside the ligand/become «biologically» inactive/nontoxic/harmless

 

Accept “dative «covalent»” for “coordinate/coordination”.

Do not accept just “chelates”.

[3 marks]

b.

Examiners report

[N/A]
a.
[N/A]
b.

Syllabus sections

Options » A: Materials » A.10 Environmental impact—heavy metals (HL only)
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