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Date May 2016 Marks available 1 Reference code 16M.3.hl.TZ0.13
Level HL Paper 3 Time zone TZ0
Command term Identify Question number 13 Adapted from N/A

Question

Spinach is an excellent source of vitamins A and C.

Identify one structural characteristic in vitamins A and D which makes them more similar to each other than they are to vitamin C using section 35 of the data booklet.

[1]
a.

The pigments from spinach were separated using chromatography. Identify Z by calculating its Rf value and using the data table.

Rf:

Z:

[1]
b.

Markscheme

A and D have one/few polar/hydroxyl/OH groups «but C has many of those»
OR
A and D have hydrocarbon/six-membered «carbon» rings «but C has heterocyclic/five-membered ring»
OR
A and D have long hydrocarbon chains/consist of mainly non-polar components

Accept other valid similarities or differences.

Accept “hydroxy/alcohol” but not “hydroxide” for “hydroxyl”.

a.

0.47 AND chlorophyll b

Accept any Rf value in the range 0.44–0.50.

b.

Examiners report

[N/A]
a.
[N/A]
b.

Syllabus sections

Options » B: Biochemistry » B.5 Vitamins
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