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Date November 2011 Marks available 1 Reference code 11N.3.sl.TZ0.C3
Level SL Paper 3 Time zone TZ0
Command term Describe Question number C3 Adapted from N/A

Question

Fuel cells convert chemical energy directly into electrical energy that can be used in applications ranging from spacecraft to remote weather stations.

Describe the composition of the electrodes in a hydrogen-oxygen fuel cell.

[1]
a.

State the half-equation at each electrode in the hydrogen-oxygen alkaline cell.

Positive electrode (cathode):

Negative electrode (anode):

[2]
b.

Markscheme

(porous) carbon/graphite electrodes (impregnated) with Pd/Pt/Ag catalysts;

Just Pb/Pt/Ag not sufficient for mark.

a.

Positive electrode (cathode):

\({{\text{O}}_2}{\text{(g)}} + {\text{2}}{{\text{H}}_2}{\text{O(l)}} + {\text{4}}{{\text{e}}^ - } \to {\text{4O}}{{\text{H}}^ - }{\text{(aq)}}\);

Negative electrode (anode):

\({{\text{H}}_2}{\text{(g)}} + {\text{2O}}{{\text{H}}^ - }{\text{(aq)}} \to {\text{2}}{{\text{H}}_2}{\text{O(l)}} + {\text{2}}{{\text{e}}^ - }\);

Ignore state symbols.

Allow e instead of \({e^ - }\).

Award [1] if equations are correct but electrodes reversed.

b.

Examiners report

The question on fuel cells was poorly answered, with very few including both graphite and a Pd or Pt or Ag metal in the composition of electrodes.

a.

Only the better candidates had no difficulty with the half-equations at each electrode in the hydrogen-oxygen alkaline fuel cell.

b.

Syllabus sections

Options » C: Energy » C.6 Electrochemistry, rechargeable batteries and fuel cells (HL only)
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