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Date November 2018 Marks available 1 Reference code 18N.2.HL.TZ0.5
Level Higher level Paper Paper 2 Time zone 0 - no time zone
Command term Identify Question number 5 Adapted from N/A

Question

The diagram shows the position of the principal lines in the visible spectrum of atomic hydrogen and some of the corresponding energy levels of the hydrogen atom.

A low-pressure hydrogen discharge lamp contains a small amount of deuterium gas in addition to the hydrogen gas. The deuterium spectrum contains a red line with a wavelength very close to that of the hydrogen red line. The wavelengths for the principal lines in the visible spectra of deuterium and hydrogen are given in the table.

Light from the discharge lamp is normally incident on a diffraction grating.

Determine the energy of a photon of blue light (435nm) emitted in the hydrogen spectrum.

[3]
a.i.

Identify, with an arrow labelled B on the diagram, the transition in the hydrogen spectrum that gives rise to the photon with the energy in (a)(i).

[1]
a.ii.

Explain your answer to (a)(ii).

[2]
a.iii.

The light illuminates a width of 3.5 mm of the grating. The deuterium and hydrogen red lines can just be resolved in the second-order spectrum of the diffraction grating. Show that the grating spacing of the diffraction grating is about 2 × 10–6 m.

[2]
b.i.

Calculate the angle between the first-order line of the red light in the hydrogen spectrum and the second-order line of the violet light in the hydrogen spectrum.

[3]
b.ii.

The light source is changed so that white light is incident on the diffraction grating. Outline the appearance of the diffraction pattern formed with white light.

[3]
b.iii.

Markscheme

identifies λ = 435 nm ✔

E = « h c λ =»  6.63 × 10 34 × 3 × 10 8 4.35 × 10 7  ✔

4.6 ×10−19 «J» ✔

a.i.

–0.605 OR –0.870 OR –1.36 to –5.44 AND arrow pointing downwards ✔

Arrow MUST match calculation in (a)(i)

Allow ECF from (a)(i)

a.ii.

Difference in energy levels is equal to the energy of the photon ✔

Downward arrow as energy is lost by hydrogen/energy is given out in the photon/the electron falls from a higher energy level to a lower one ✔

a.iii.

λ 2 Δ λ = 656.20 0.181 × 2 = 1813 «lines» ✔

so spacing is  3.5 × 10 3 1813  «= 1.9 × 10−6 m» ✔

 

Allow use of either wavelength or the mean value

Must see at least 2 SF for a bald correct answer

b.i.

2 × 4.1 × 10−7 = 1.9 × 10−6 sin θv seen

OR

6.6 × 10−7 = 1.9 × 10−6 sin θr seen ✔

 

θv = 24 − 26 «°»

OR

θr = 19 − 20 «°» ✔

 

Δθ = 5 − 6 «°» ✔

 

For MP3 answer must follow from answers in MP2

For MP3 do not allow ECF from incorrect angles

b.ii.

centre of pattern is white ✔

coloured fringes are formed ✔

blue/violet edge of order is closer to centre of pattern

OR

red edge of order is furthest from centre of pattern ✔

the greater the order the wider the pattern ✔

there are gaps between «first and second order» spectra ✔

b.iii.

Examiners report

[N/A]
a.i.
[N/A]
a.ii.
[N/A]
a.iii.
[N/A]
b.i.
[N/A]
b.ii.
[N/A]
b.iii.

Syllabus sections

Core » Topic 7: Atomic, nuclear and particle physics » 7.1 – Discrete energy and radioactivity
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