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Date November 2016 Marks available 1 Reference code 16N.3.hl.TZ0.28
Level HL Paper 3 Time zone TZ0
Command term Outline Question number 28 Adapted from N/A

Question

Technetium-99m is the most widely used medical radioisotope. It is usually made on-site in medical facilities from isotopes of molybdenum.

Deduce equations for the following nuclear reactions:

(i) Molybdenum-98 absorbs a neutron.

(ii) The isotope produced in (a) (i) decays into technetium-99m.

[2]
a.

Molybdenum-99 has a half-life of 66 hours, while technetium-99m has a half-life of 6 hours. Outline why technetium-99m is made on-site.

[1]
b.

Outline two reasons, other than its half-life, why technetium-99m is so useful in medical diagnosis.

[2]
c.

Outline the nature of the radioactive waste that is generated by the use of technetium-99m in medical diagnosis.

[1]
d.

Markscheme

i

42 98 M o 0 1 n 42 99 M o

Accept 98Mo + 1n/n → 99Mo.


ii

42 99 Mo 43 99 m Tc + 1 0 β

Accept “ 1 0 e ” for “ 1 0 β ”.

Accept “ 99 M o 99 m T c + β ”.

Accept “ 1 0 e / e / e ” for “ β ”.

Do not penalize “ 99 T c ” for “ 99 m T c ”.

a.

molybdenum-99 can be easily transported «before it decays»/more stable
OR
«most of» technetium-99m will decay during transportation

Do not accept just “short half-life of Tc-99m”

b.

emits gamma rays
OR
emissions escape from body
OR
emissions detected by gamma camera
OR
radiation dose is low

chemically reactive/versatile/transition metal bonds to a range of «biologically active» substances

Do not accept “short half-life of Tc-99m”.
Accept “energy of photons produced is «relatively» low” and “no high energy beta emission” for M1.
Accept “…has ability to form tracers” for “…bonds to a range of «biologically active» substances".

c.

low-level «radioactive» waste/LLW
OR
small amounts of ionizing radiation for short time

d.

Examiners report

[N/A]
a.
[N/A]
b.
[N/A]
c.
[N/A]
d.

Syllabus sections

Options » D: Medicinal chemistry » D.6 Environmental impact of some medications
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