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Date November 2016 Marks available 1 Reference code 16N.3.hl.TZ0.28
Level HL Paper 3 Time zone TZ0
Command term Outline Question number 28 Adapted from N/A

Question

Technetium-99m is the most widely used medical radioisotope. It is usually made on-site in medical facilities from isotopes of molybdenum.

Deduce equations for the following nuclear reactions:

(i) Molybdenum-98 absorbs a neutron.

(ii) The isotope produced in (a) (i) decays into technetium-99m.

[2]
a.

Molybdenum-99 has a half-life of 66 hours, while technetium-99m has a half-life of 6 hours. Outline why technetium-99m is made on-site.

[1]
b.

Outline two reasons, other than its half-life, why technetium-99m is so useful in medical diagnosis.

[2]
c.

Outline the nature of the radioactive waste that is generated by the use of technetium-99m in medical diagnosis.

[1]
d.

Markscheme

i

\({}_{{\rm{42}}}^{98}{\rm{Mo}}\) + \({}_{{\rm{0}}}^{1}{\rm{n}}\) → \({}_{{\rm{42}}}^{99}{\rm{Mo}}\)

Accept 98Mo + 1n/n → 99Mo.


ii

\({}_{42}^{99}{\text{Mo}} \to {}_{43}^{99\,{\text{m}}}{\text{Tc}} + {}_{ - 1}^0\beta \)

Accept “ \({}_{ - 1}^0e\)” for “ \({}_{ - 1}^0\beta \)”.

Accept “ \({}^{99}Mo \to {}_{}^{99\,{\text{m}}}Tc + \beta \)”.

Accept “ \({}_{ - 1}^0e/{e^ - }/e\)” for “\(\beta \)”.

Do not penalize “ \({}_{}^{99}Tc\)” for “ \({}_{}^{99\,{\text{m}}}Tc\)”.

a.

molybdenum-99 can be easily transported «before it decays»/more stable
OR
«most of» technetium-99m will decay during transportation

Do not accept just “short half-life of Tc-99m”

b.

emits gamma rays
OR
emissions escape from body
OR
emissions detected by gamma camera
OR
radiation dose is low

chemically reactive/versatile/transition metal bonds to a range of «biologically active» substances

Do not accept “short half-life of Tc-99m”.
Accept “energy of photons produced is «relatively» low” and “no high energy beta emission” for M1.
Accept “…has ability to form tracers” for “…bonds to a range of «biologically active» substances".

c.

low-level «radioactive» waste/LLW
OR
small amounts of ionizing radiation for short time

d.

Examiners report

[N/A]
a.
[N/A]
b.
[N/A]
c.
[N/A]
d.

Syllabus sections

Options » D: Medicinal chemistry » D.6 Environmental impact of some medications

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