Explain the mechanism of the reaction using curly arrows to represent the movement of electron pairs.

Below are two isomers, A and B, with the molecular formula C₄H₉Br.

Explain the mechanism of the nucleophilic substitution reaction with NaOH(aq) for the isomer that reacts almost exclusively by an S_N2 mechanism using curly arrows to represent the movement of electron pairs.

State the type of bond fission that takes place in a S_N1 reaction.

State the type of solvent most suitable for the reaction.

State the reagents used in the nitration of benzene.

Outline why the rate of reaction of the similar bromo-compounds is faster.

Deduce the product of the complete reduction reaction in (e)(i).

Write the equation for the production of the active nitrating agent from concentrated sulfuric and nitric acids.

In which order should the reagents be used to convert benzene into phenylamine (aniline)?

State the reagent used to convert benzoic acid to phenylmethanol (benzyl alcohol), C₆H₅CH₂OH.

Which is a major product of the electrophilic addition of hydrogen chloride to propene?

A. ClCH₂CH=CH₂

B. CH₃CH(Cl)CH₃

C. CH₃CH₂CH₂Cl

D. CH₃CH=CHCl

State the reagents and the name of the mechanism for the nitration of benzene.

Explain the mechanism of the reaction between 2-bromo-2-methylpropane, (CH₃)₃CBr, and aqueous sodium hydroxide, NaOH (aq), using curly arrows to represent the movement of electron pairs.

State the reagents used to convert benzene to nitrobenzene and the formula of the electrophile formed.

Sketch the mechanism using curly arrows to represent the movement of electrons.

When the product X is reacted with NaOH in a hot alcoholic solution, C₂H₃Cl is formed. State the role of the reactant NaOH other than as a nucleophile.

State the reagents used in the two-stage conversion of nitrobenzene to aniline.

Which class of compound is formed when a ketone is reduced?

A. primary alcohol

B. secondary alcohol

C. ether

D. carboxylic acid

Nitrobenzene, C₆H₅NO₂, can be converted to phenylamine via a two-stage reaction.

In the first stage, nitrobenzene is reduced with tin in an acidic solution to form an intermediate ion and tin(II) ions. In the second stage, the intermediate ion is converted to phenylamine in the presence of hydroxide ions.

Formulate the equation for each stage of the reaction.

Draw the structure of the intermediate formed stating its shape.

Suggest how this product could be synthesized in one step from butanoic acid.

What will be the major product in the reaction between but-1-ene and $\mathrm{Hbr}$?

A.  2-bromobut-1-ene

B.  1-bromobut-1-ene

C.  2-bromobutane

D.  1-bromobutane

Write an equation for the reaction of the major product with aqueous sodium hydroxide to produce a C₃H₈O compound, showing structural formulas.

In which compound is the halogen substituted the most rapidly by aqueous hydroxide ions?

A. (CH₃)₃CCl

B. (CH₃)₃CI

C. CH₃CH₂CH₂CH₂Cl

D. CH₃CH₂CH₂CH₂I

State an equation for the formation of NO₂⁺.

Write an equation for the reaction between the acids to produce the electrophile, NO₂⁺.

Predict, giving a reason, the major product of reaction between but-1-ene and steam.

Explain the mechanism for the nitration of benzene, using curly arrows to indicate the movement of electron pairs.

Which is most likely to hydrolyse via a S_N1 mechanism?

A.  CH₃CHBrCH₂CH₃

B.  (CH₃)₂CHBr

C.  (CH₃)₃CBr

D.  CH₃CH₂CH₂CH₂Br

The benzene ring of phenylethene reacts with the nitronium ion, NO₂⁺, and the C=C double bond reacts with hydrogen bromide, HBr.

Compare and contrast these two reactions in terms of their reaction mechanisms.

Similarity: 

Difference:

Which is the electrophile in the nitration of benzene?

A.  ${\mathrm{HNO}}_3$

B.  ${{\mathrm{NO}}_2}^{+}$

C.  ${{\mathrm{NO}}_2}^{-}$

D.  ${{\mathrm{NH}}_4}^{+}$

Propene is reacted first with hydrogen chloride to produce X which is then reacted with aqueous sodium hydroxide to give Y. Finally, Y is reacted with excess acidified potassium dichromate solution.

$$\text{C}{\text{H}}_{\text{3}}\text{CHC}{\text{H}}_{\text{2}}\stackrel{\text{HCL}}{\to }\text{X}\stackrel{\text{NaOH(aq)}}{\to }\text{Y}\stackrel{{\text{H}}^{+}/\text{C}{\text{r}}_2{{\text{O}}_7}^{2-}\text{(aq)}}{\to }\text{Z}$$

What is the major product, Z? 

A.     CH₃CH(OH)CH₃

B.     CH₃COCH₃

C.     CH₃CH₂CHO

D.     CH₃(CH₂)₂COOH

Explain the mechanism of the reaction between chloroethane and aqueous sodium hydroxide, $\mathrm{NaOH} \left(\mathrm{aq}\right)$, using curly arrows to represent the movement of electron pairs.

Explain the mechanism of the reaction between 1-bromopropane, CH₃CH₂CH₂Br, and aqueous sodium hydroxide, NaOH (aq), using curly arrows to represent the movement of electron pairs.

Compare and contrast the mechanisms by which 1-chlorobutane, CH₃CH₂CH₂CH₂Cl, and 2-chloro-2-methylpropane, (CH₃)₃CCl, react with aqueous sodium hydroxide, giving two similarities and one difference.

Explain why the reaction produces more (CH₃)₃COH than (CH₃)₂CHCH₂OH.

Which product is formed when CH₃COCH₂CH₃ is reduced with sodium borohydride?

A.  CH₃CH₂CH₂CHO

B.  CH₃CH₂CH₂CH₂OH

C.  CH₃CH(OH)CH₂CH₃

D.  CH₃CH₂CH₂COOH